I'm not specifically familiar with the Pegasus, but it's a Mendel derivative and the Mendel traditionally uses an origin at (0,0) (bed center at (100,100) or thereabouts). Slic3r used to use bed center, but when they now say origin, they mean the coordinates of the bed corner at minimum x and minimum y. Set that to (0,0) and the bed to 200 x 200 and Slic3r will center your parts at the point where the nozzle goes when you command G1 X100 Y100, which is probably bed center.