Your endstop set correctly? your firmware configured correctly? was the model definitely centered in the slicer?
Try telling it to go to 100, 100 and see if that is center. Also check 0,100 and 100, 0. This should highlight the problem anyway.
If you need some help, or don't understand what I just said, feel free to send me a PM anytime
Printer: Prusa i3, 2 E3D v6 Hotends, Arduino + RAMPS 1.4 with a Bypassed 5V Regulator, 400w Insignia ATX PSU, Custom Designed Bowden Extruders